Synthesis of 3,3-dimethyl-1-phenyl-2-phenylethynylcyclopropene - the first conjugated alkynylcyclopropene

Autor:	V. A. Gindin, Yu. V. Dorofeeva, V. V. Semenovskii, Mikhail A. Kuznetsov, A. N. Studenikov
Rok vydání:	1992
Předmět:	chemistry.chemical_compound Azo compound Chemistry Organic Chemistry Drug Discovery 1 3-Dipolar cycloaddition Photodissociation Organic chemistry Conjugated system Biochemistry Medicinal chemistry
Zdroj:	Tetrahedron. 48:1269-1280
ISSN:	0040-4020
Popis:	The 1,3-cycloaddition reaction of 2-diazopropane with diphenyldiacetylene leads to the mixture of 3,3-dimethyl-5-phenyl-4-phenylethynyl-3H-pyrazole, 3,3-dimethyl-4-phenyl-5-phenylethynyl-3H-pyrazole, and 3,3,3′,3′-tetramethyl-4′,5-diphenyl-4,5′-bi-3H-pyrazolyl. Photolysis of both 3H-pyrazoles gives the title phenylethynylcyclopropene.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d593a661f06bf2e3b97b9c85868c4f0c https://doi.org/10.1016/s0040-4020(01)90789-6 Zobrazit plný text záznamu