The first use of tri(1-naphthyl)phosphine oxide as ligand for rhenium(I)- complexes from phosphine via a one-pot approach
| Autor: | Malaichamy Sathiyendiran, T. Arumuganathan, Ramar Arumugam, Bhaskaran Shankar |
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| Rok vydání: | 2021 |
| Předmět: |
Phosphine oxide
010405 organic chemistry Ligand Organic Chemistry chemistry.chemical_element Rhenium 010402 general chemistry 01 natural sciences Biochemistry Solid state structure 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound chemistry Chloranilic acid Polymer chemistry Materials Chemistry Physical and Theoretical Chemistry Phosphine |
| Zdroj: | Journal of Organometallic Chemistry. 933:121657 |
| ISSN: | 0022-328X |
| Popis: | Tri(1-naphthyl)phosphine oxide (Np3P=O) coordinated complexes fac-[{Re(CO)3(Np3P=O)}2L] (1-2) were prepared from tri(1-naphthyl)phosphine (Np3P), H2-L (2,5-dihydroxy-1,4-benzoquinone for 1/chloranilic acid for 2), and Re2(CO)10 in a multi-component one-pot approach. A hard Np3P=O was formed in situ from soft Np3P during the reaction process. The solid state structure of 2 reveals that chloranilato is sandwiched between two naphthyl units, controlled by both aromatic π⋅⋅⋅π⋅⋅⋅π- and Cl⋅⋅⋅π- contacts. This is the first report on metal-complexes of tri(1-naphthyl)phosphine oxide. |
| Databáze: | OpenAIRE |
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