On the intramolecular ordering and the mobility mechanism in solutions of comb-like polyalkyl methacrylates

Autor:	V.P. Malinovskaya, L.L. Burshtein, V.P. Shibayev, T.I. Borisova
Rok vydání:	1991
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Dipole chemistry Chemical physics Intramolecular force Polymer chemistry General Engineering Relaxation process Polymer Polarization (waves) Methacrylate Toluene
Zdroj:	Polymer Science U.S.S.R.. 33:1993-1998
ISSN:	0032-3950
Popis:	The dipole polarization relaxation method was used to investigate molecular mobility in solutions of polyhexadecylmethacrylate (PMA-16) in toluene. The previously obtained data on molecular mobility in polymers of type PMA-n (n = 1, 4, 8, 10, 16 and 22) have been analysed. It is shown that a new relaxation process appears as a result of the partial aggregation of side-chains in the case where n > 10.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d58590b05a0a11cc7a02ca12cc895a42 https://doi.org/10.1016/0032-3950(91)90098-b Zobrazit plný text záznamu