Ligand-controlled chemoselectivity in gold-catalyzed cascade cyclization of 1,4-diene-tethered 2-alkynylbenzaldehydes

Autor: Jichao Chen, Rui Hu, Qing Bao, Dandan Shang, Lei Yu, Philip Wai Hong Chan, Weidong Rao
Rok vydání: 2022
Předmět:
Zdroj: Organic Chemistry Frontiers. 9:6520-6529
ISSN: 2052-4129
Popis: A synthetic method that relies on the gold(i)-catalyzed cascade annulation of skipped 1,4-diene-tethered 2-alkynylbenzaldehydes for the chemo- and stereoselective assembly polycyclic bridged-pyrrolidines and -azepines is described.
Databáze: OpenAIRE