Electronic and Steric Influences on the Rate and Energetics of THF and MenTHF (n= 1, 2) Displacement from LRe(CO)2(L = Tp, Tp*, Cp*) Fragments by Acetonitrile

Autor:	Ashfaq A. Bengali, Matthew N. Hart, Benjamin K. Mezick, Shahnaz Fereshteh
Rok vydání:	2003
Předmět:	Steric effects Solvent molecule Chemistry Stereochemistry Lability Organic Chemistry Energetics Medicinal chemistry Inorganic Chemistry Solvent Metal chemistry.chemical_compound visual_art visual_art.visual_art_medium Reactivity (chemistry) Physical and Theoretical Chemistry Acetonitrile
Zdroj:	Organometallics. 22:5436-5440
ISSN:	1520-6041 0276-7333
Popis:	The dissociative displacement of the THF solvent molecule from LRe(CO)2−THF (L = Tp, Tp*, Cp*) and of MenTHF (n = 1, 2) from TpRe(CO)2−MenTHF by acetonitrile is studied. While the reactivity of the Re−THF bond depends on the electronic properties of the ancillary ligands (Tp, Tp*, Cp*) attached to the metal center, the lability of the Re−MenTHF bond is primarily influenced by the steric demands of the departing solvent.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d56841f046b1eef9f516b9ed6c9a8588 https://doi.org/10.1021/om0341000 Zobrazit plný text záznamu