Synthesis and electrochemical and EPR investigations of the 48/49-electron [(.eta.5-C5H4Me)MnFe2(.eta.5-C5H5)2(.mu.-CO)2(.mu.-NO)(.mu.3-NO)]n series (n = 0, 1-): stereochemical-bonding analysis of the redox-generated change in geometry of a triangular mixed-metal cluster
| Autor: | Kimberly A. Kubat-Martin, Lawrence F. Dahl, Brook. Spencer |
|---|---|
| Rok vydání: | 1987 |
| Předmět: |
chemistry.chemical_classification
Chemistry Stereochemistry Organic Chemistry Crystal structure Electrochemistry Redox law.invention Inorganic Chemistry Crystallography law X-ray crystallography Molecule Physical and Theoretical Chemistry Cyclic voltammetry Electron paramagnetic resonance Inorganic compound |
| Zdroj: | Organometallics. 6:2580-2587 |
| ISSN: | 1520-6041 0276-7333 |
| DOI: | 10.1021/om00155a021 |
| Popis: | (η 5 -C 5 H 4 Me)MnFe 2 (η 5 -C 5 H 5 ) 2 (μ-CO) 2 (μ-NO)(μ 3 -NO) cristallise dans le systeme monoclinique, groupe d'espace P2 1/c et sa structure est affinee jusqu'a R=0,036. [K(2,2,2-crypt)] + [(η-C 5 H 4 Me)MnFe 2 (η 5 -C 5 H 5 ) 2 (μ-CO) 2 (μ-NO)(μ 3 -NO)] a cristallise dans le systeme triclinique, groupe d'espace PI et sa structure est affinee jusqu'a R=0,069 |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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