ChemInform Abstract: Functionalized o-Bis(chloromethyl)pyridines as Precursors for Pyridine o-Quinodimethane Analogues and Their (4+2) Cycloadducts
Autor: | Peter R. Carly, Frans Compernolle, Georges J. Hoornaert |
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Rok vydání: | 2010 |
Předmět: | |
Zdroj: | ChemInform. 26 |
ISSN: | 0931-7597 |
Popis: | From oxazinones 4 , precursors for pyridine o-quinodimethane analogues are made accessible via cycloaddition with 1,4-dichloro-2-butyne and propargyl chloride. Subsequent 1,4-elimination of the polyfunctional o-bis(chloromethyl)-pyridines affords both 2,3- and 3,4-dimethylene compounds, which are trapped in situ with various dienophiles. |
Databáze: | OpenAIRE |
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