Flash Photolysis of H2O2 Vapor in the Presence of D2, Ar, and H218O

Autor:	N. R. Greiner
Rok vydání:	1966
Předmět:	Reaction rate constant Absorption spectroscopy Chemistry Analytical chemistry General Physics and Astronomy Flash photolysis Molecule Singlet state Physical and Theoretical Chemistry Kinetic energy
Zdroj:	The Journal of Chemical Physics. 45:99-103
ISSN:	1089-7690 0021-9606
DOI:	10.1063/1.1727364
Popis:	The flash photolysis of H2O2 by itself, and in the presence of D2, Ar, and H218O, was studied by the technique of kinetic absorption spectroscopy. The only observable primary products were OH(2Π½) and OH(2Π32). These ground‐state levels were populated in a ratio of ∼1:1, respectively, conforming to what is observed with the halogens.The contribution of Reaction (a) to the primary process was shown in a direct way to be no more than 20% of that of (b). Reaction (c) followed by (d) was shown to make no significant contribution to the OH concentration during the time of our experiments (
Databáze:	OpenAIRE
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