N,N-bis(trimethylsilyl)methoxymethylamine as a convenient synthetic equivalent for +CH2NH2: primary aminomethylation of esters
Autor: | Toshiaki Morimoto, Minoru Sekiya, Kohji Okano |
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Rok vydání: | 1984 |
Předmět: | |
Zdroj: | Journal of the Chemical Society, Chemical Communications. :883 |
ISSN: | 0022-4936 |
Popis: | The introduction of a primary aminomethyl unit at the α-position of esters can be achieved in high yield by the silyl trifluoromethanesulphonate-catalysed reaction of ketene silyl acetals (2) with N,N-bis(trimethylsilyl)methoxymethylamine (1). |
Databáze: | OpenAIRE |
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