Adsorption of nitrogen on iron and manganese
Autor: | E. A. Zelyaeva, N. N. Kavtaradze |
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Rok vydání: | 1970 |
Předmět: | |
Zdroj: | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 19:2465-2467 |
ISSN: | 1573-9171 0568-5230 |
DOI: | 10.1007/bf00859103 |
Popis: | 1. Iron and manganese manifest similar properties as regards the adsorption of nitrogen in the entire range of studied temperatures and pressures. 2. Two types of adsorption are observed at -195° -irreversible and reversible. Only the reversible adsorption of nitrogen occurs at -78°. 3. The isosteric heat of adsorption, calculated from the two temperatures -195 and -78°, is close to 1 kcal/mole. 4. A slow adsorption of nitrogen, bearing an activated character, is observed at 0, 50 and 100°. 5. At all of the studied temperatures the degree to which the manganese surface is covered is greater than in the case of iron. |
Databáze: | OpenAIRE |
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