Copper(I)-Catalyzed Thiolation of C–H Bonds for the Synthesis of Sulfenyl Pyrroles and Indoles

Autor:	Yu-Yuan Hei, Jian-Lan Song, Chen-Liang Deng, Xin-Chen Zhan, Wei Xu, Xing-Guo Zhang
Rok vydání:	2018
Předmět:	chemistry.chemical_compound 010405 organic chemistry Chemistry Organic Chemistry chemistry.chemical_element 010402 general chemistry Copper(I) iodide 01 natural sciences Copper Combinatorial chemistry Catalysis 0104 chemical sciences
Zdroj:	Synthesis. 51:545-551
ISSN:	1437-210X 0039-7881
Popis:	A novel and convenient copper(I)-catalyzed thiolation of C–H bonds of pyrroles and indoles is developed for the synthesis of sulfenyl pyrroles and indoles. Dual C–H thiolation reactions are observed for pyrroles. A wide range of pyrroles and indoles undergo the C–H thiolation smoothly with various disulfides and diselenides to generate the corresponding heteroaryl thioethers in moderate to excellent yields.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d4f1e310783362dbb19427518ed892be https://doi.org/10.1055/s-0037-1610295 Zobrazit plný text záznamu