Chemoenzymatic autocatalytic Baeyer–Villiger oxidation

Autor:	Beata Krystyna Pchelka, Mirjana Gelo-Pujic, Eryka Guibé-Jampel
Rok vydání:	1998
Předmět:	Autocatalysis Dry media reaction chemistry.chemical_compound Primary (chemistry) chemistry biology biology.protein Organic chemistry Lipase Peroxide Baeyer–Villiger oxidation
Zdroj:	Journal of the Chemical Society, Perkin Transactions 1. :2625-2628
ISSN:	1364-5463 0300-922X
DOI:	10.1039/a804426k
Popis:	Autocatalytic Baeyer–Villiger oxidation of cyclic ketones to lactones mediated by lipases has been achieved under extremely mild conditions in dry media using urea–hydrogen peroxide as the primary oxidant. Lipase catalysed perhydrolysis is enantiospecific and gives 6-substituted caprolactones or the corresponding hydroxy acids in enantiomerically enriched form.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d4ab734ce200d2b725f580ae83ffcdb8 https://doi.org/10.1039/a804426k Zobrazit plný text záznamu