ChemInform Abstract: Intramolecular Electrophilic Rearrangements in Saturated Acyclic Systems. Reactions of Bis-carbanions with Isocyanates

Autor:	Yu. G. Gololobov, Pavel V. Petrovskii, T. I. Guseva, N. G. Senchenya
Rok vydání:	2010
Předmět:	inorganic chemicals chemistry Hydrogen Nitrogen atom Intramolecular force Electrophile chemistry.chemical_element General Medicine Photochemistry Carbon Medicinal chemistry Carbanion
Zdroj:	ChemInform. 33
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200201049
Popis:	The reactions of mono- and bis-isocyanates with bis-carbanions whose COOAlk groups at the anionic centers do not contain acidic hydrogen atoms proceed unusually to form bis-carbamates (including oligomeric carbamates) due to migration of the alkoxycarbonyl groups from the carbon to the nitrogen atom.
Databáze:	OpenAIRE
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