Effect of State of Condensation on the Ionization Potential of Associated Liquids

Autor:	G.A.St. John, H. R. Gloria, R. F. Reinisch, Michael Anbar
Rok vydání:	1972
Předmět:	Heavy water Photodissociation Condensation Quantum yield Photoionization Photochemistry chemistry.chemical_compound chemistry Excited state Physics::Atomic and Molecular Clusters Physics::Chemical Physics Ionization energy Astrophysics::Galaxy Astrophysics Electron ionization
Zdroj:	Water Structure at the Water-Polymer Interface ISBN: 9781461586838
DOI:	10.1007/978-1-4615-8681-4_9
Popis:	Liquid water and alcohols have been shown to undergo photoionization when subjected to vacuum ultraviolet in the range 210-180 nm. Hydrated electrons have been identified as products of photolysis in liquid water by a number of characteristic reactions using competition kinetics as a quantitative criterion. The reactions e− aq + SF6, e− aq + H3O+, and e− aq + Cd++ have been used as the principal analytical tools of investigation. The photoproduction of electrons was shown to be the result of a single photon process. A parallel investigation of the photodissociation of water to H + OH suggests that photoionization and photodissociation of liquid water involve the same excited state; the cross section for photodissociation being about ten times larger than for photoionization.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d4919657edfe5d8905ed2f4a231318f4 https://doi.org/10.1007/978-1-4615-8681-4_9 Zobrazit plný text záznamu