Ultrafast green microwave-assisted synthesis of high-entropy oxide nanoparticles for Li-ion battery applications
| Autor: | Sun Ig Hong, Hossein Minouei, Dae Eun Kim, Gi Hwan Kim, Mehdi Kheradmandfard, Ali Kasebi Vayghan, Nikolai Tsvetkov, Seyed Farshid Kashani-Bozorg |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Battery (electricity)
Materials science Oxide chemistry.chemical_element Nanoparticle 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences 0104 chemical sciences Anode Ion chemistry.chemical_compound chemistry Chemical engineering visual_art visual_art.visual_art_medium General Materials Science Lithium Ceramic 0210 nano-technology Nanoscopic scale |
| Zdroj: | Materials Chemistry and Physics. 262:124265 |
| ISSN: | 0254-0584 |
| DOI: | 10.1016/j.matchemphys.2021.124265 |
| Popis: | In this study, a novel ultrafast facile green microwave-assisted method was developed for the synthesis of high-entropy oxide (HEO) (Mg, Cu, Ni, Co, Zn)O nanoparticles for the first time. The results indicated that all the five metallic elements were uniformly distributed in the single-phase rocksalt structure of the HEO nanoparticles. The particle-size distribution was within the range of 20–70 nm, with the average size of 44 nm. When used as anode materials for Li-ion batteries, the HEO nanoparticles exhibited remarkable lithium storage properties with the impressive stability as was demonstrated during 1000 cycles at 1 A/g. The exceptional advantages of the proposed method in this work, including ultrafast speed (few minutes), low temperature, nanoscale and high-purity products, and low cost, make it an excellent synthesis technique for application in newly developed high-entropy ceramics, particularly for Li-ion batteries. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect