Ionization of xenon atoms in high Rydberg states by collision with molecules

Autor:	G. W. Foltz, F. G. Kellert, G. F. Hildebrandt, R. F. Stebbings, K. A. Smith, F. B. Dunning, W. P. West, C. J. Latimer
Rok vydání:	1977
Předmět:	Chemistry General Physics and Astronomy chemistry.chemical_element Ion symbols.namesake Reaction rate constant Xenon Excited state Ionization Physics::Atomic and Molecular Clusters Rydberg formula symbols Molecule Physical and Theoretical Chemistry Atomic physics Excitation
Zdroj:	The Journal of Chemical Physics. 67:1352-1359
ISSN:	1089-7690 0021-9606
DOI:	10.1063/1.435034
Popis:	Ionization of xenon atoms in single highly excited states ‖nf≳ (where 25⩽n⩽40) by collisions with CCl4, CCl3F, and SF6 has been investigated. Absolute rate constants for Xe+ production are reported together with the identities of the major negatively charged species produced in the collisions. Cross sections determined from these rate constants are also given. The data lend support to the theoretical model, which views such collisions as being dominated by the interaction between the target molecules and the excited electron, with the Xe+ ion core playing a minor role.
Databáze:	OpenAIRE
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