The mass spectrum of -octadecyl benzoate. Hydrogen migration in the formation of C18H36⨥ and C7H7O2+

Autor:	E.K. Fields, E.S. Kuhn, L. C. Leitch, I. Puskas, Thomas A. Sullivan, Seymour Meyerson
Rok vydání:	1983
Předmět:	Crystallography Hydrogen Deuterium Chemistry Stereochemistry Mass spectrum chemistry.chemical_element Hydrogen atom Spectroscopy Benzoates
Zdroj:	International Journal of Mass Spectrometry and Ion Physics. 47:479-482
ISSN:	0020-7381
DOI:	10.1016/0020-7381(83)87238-6
Popis:	The electron-impact mass spectra of a series of specifically deuterated n-octadecyl benzoates define the positions from which hydrogen atom migration occurs in the reaction paths leading to C18H36⨥ and C7H7O2. The migration step in the path leading to C18H36⨥ and the first of the two migration steps in that leading to C7H7O2 appear to be one and the same, occurring from carbons 1 to 7, with the maximum contribution from C-3. The second migration step in the path leading to C7H7O2+ appears to occur nonselectively from all positions in the octadecyl group.
Databáze:	OpenAIRE
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