Synthesis and structures of two new Cu(I) frameworks bearing1,3-bis(4-pyridyl)propane and inorganic linkers

Autor:	Zilu Chen, Bo Li, Yuning Liang, Zhaobo Hu, Wenqiang Ju
Rok vydání:	2016
Předmět:	chemistry.chemical_classification 010405 organic chemistry Infrared spectroscopy General Chemistry Crystal structure Polymer 010402 general chemistry 01 natural sciences 0104 chemical sciences chemistry.chemical_compound chemistry Propane Polymer chemistry Topology (chemistry)
Zdroj:	Journal of Chemical Sciences. 128:893-898
ISSN:	0973-7103 0974-3626
DOI:	10.1007/s12039-016-1100-6
Popis:	Two novel metal-organic coordination polymers [Cu2(bpp)Cl2] (1) and [Cu2(bpp)2SO4] ⋅DMF⋅ 3H2O (2) were prepared from the reactions of 1,3-bis(4-pyridyl)propane (bpp) with CuCl2 and CuSO4, respectively, which were characterized by single-crystal X-ray diffraction analysis, elemental analysis, IR spectroscopy and powder X-ray diffraction analysis. 1features inorganic one-dimensional [Cu2Cl2] ribbons, which are linked by the bpp ligands to form a three-dimensional metal-organic framework exhibiting a 3,3,4-connected 3-nodal topology. 2presents [Cu2SO4] inorganic dinuclear secondary building blocks which are further connected by the bpp ligands to construct a two-dimensional framework featuring flask-stacking appearance. They are typical examples of metal-organic framework constructed by the synergistic use of organic and inorganic linkers.
Databáze:	OpenAIRE
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