Thermochemical Properties of Si2F6 and SiF4 in Gas and Condensed Phases
| Autor: | Tetsuji Noda, John L. Lyman |
|---|---|
| Rok vydání: | 2001 |
| Předmět: | |
| Zdroj: | Journal of Physical and Chemical Reference Data. 30:165-186 |
| ISSN: | 1529-7845 0047-2689 |
| DOI: | 10.1063/1.1364519 |
| Popis: | The available data for determining the thermochemical parameters for Si2F6 and SiF4 has been assembled. With this information, the thermochemical functions for Si2F6 and SiF4 have been calculated as ideal gases in the harmonic oscillator approximation. These results are presented in the format of the NIST–JANAF Thermochemical Tables, as well as in the format of the CHEMKIN Thermochemical Database. Using the vapor pressure data, the thermochemical parameters for Si2F6 in the solid phase and SiF4 in both the solid and liquid phases have been calculated. These results are compared with available experimental and calculated data. The earlier results are in good agreement with our results. However, the Si2F6 results were not previously available in the JANAF format, and the results for both species are on a much firmer footing with the new experimental data we used. The anharmonicity constants measured earlier for SiF4 permitted a determination of the effect of anharmonicity on the thermochemical properties fo... |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|