Copper and triphenylphosphine-promoted sulfenylation of quinones with arylsulfonyl chlorides

Autor:	Huida Wan, Dawei Wang, Xiaoli Yu, Xingle Xu, Qiujin Wu, Zhaojun Xu
Rok vydání:	2016
Předmět:	Alternative methods chemistry.chemical_compound chemistry 010405 organic chemistry General Chemical Engineering Organic chemistry chemistry.chemical_element General Chemistry Triphenylphosphine 010402 general chemistry 01 natural sciences Copper 0104 chemical sciences
Zdroj:	RSC Advances. 6:62298-62301
ISSN:	2046-2069
Popis:	The efficient copper and triphenylphosphine-promoted sulfenylation of quinones with arylsulfonyl chlorides has been developed under mild conditions with moderate to good yields. Significantly, this provides an alternative method to synthesise arylthioquinone derivatives. This is the first time that arylthioquinones with arylsulfonyl chlorides as starting material have been prepared, which avoids the use of the awful smelling thioalcohols and thiophenols.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d429b4aa62201c3fe3bf4b7640f45cb5 https://doi.org/10.1039/c6ra11301j Zobrazit plný text záznamu