A G4·K+ hydrogel made from 5′-hydrazinoguanosine for remediation of α,β-unsaturated carbonyls
| Autor: | Jeffery T. Davis, Songjun Xiao |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
010405 organic chemistry
Environmental remediation Acrolein Metals and Alloys General Chemistry 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Adduct Gas phase chemistry.chemical_compound chemistry Cascade reaction Methyl vinyl ketone Materials Chemistry Ceramics and Composites Organic chemistry Methyl acrylate |
| Zdroj: | Chemical Communications. 54:11300-11303 |
| ISSN: | 1364-548X 1359-7345 |
| Popis: | A G4·K+ hydrogel made from 5′-hydrazinoguanosine and KCl reacts with α,β-unsaturated carbonyls of different electrophilicities (acrolein, methyl vinyl ketone and methyl acrylate) in water and the gas phase to form cyclic adducts. This aza-Michael addition/cyclization domino reaction by the 5′-hydrazino G4·K+ hydrogel has promise for environmental remediation of toxic α,β-unsaturated carbonyls from water and the atmosphere. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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