Diverse Reactivity of an Iron–Aluminium Complex with Substituted Pyridines
| Autor: | Nikolaus Gorgas, Andrew White, Mark Crimmin |
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| Rok vydání: | 2022 |
| DOI: | 10.26434/chemrxiv-2022-vzf0w |
| Popis: | The reaction of an Fe–Al complex with an array of substituted pyridines is reported. Depending on the substitution pattern of the substrate site-selective sp2 or sp3 C–H bond activation is observed. A series of reaction products are observed based on (i) C–Al bond formation, (ii) C–C bond formation by nucleophilic addition or (iii) deprotonation of the β-diketiminate ligand. A divergent set of mechanisms involving a common intermediate is proposed. |
| Databáze: | OpenAIRE |
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