Possibility of Mo2O6 formation at high temperatures in the range of pressures from 1 to 1 × 10−5 bar
| Autor: | E. V. Antonov, D. V. Kostomarov, S. A. Kobzareva, Kh. S. Bagdasarov |
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| Rok vydání: | 2010 |
| Předmět: |
Range (particle radiation)
Gibbs free energy minimization Chemistry Materials Science (miscellaneous) Molybdenum oxide Metallurgy Analytical chemistry chemistry.chemical_element Monoxide Chemical synthesis Inorganic Chemistry Metal Molybdenum visual_art visual_art.visual_art_medium Physical and Theoretical Chemistry Bar (unit) |
| Zdroj: | Russian Journal of Inorganic Chemistry. 55:1433-1437 |
| ISSN: | 1531-8613 0036-0236 |
| DOI: | 10.1134/s0036023610090160 |
| Popis: | Gibbs free energy minimization was used to consider the formation of complex molybdenum oxide (Mo2O6) at 2400 K in the range of pressures from 1 to 1 to 1 × 10−5 bar for the basic component ratio Mo: O2 = 1: 1. Several ways are shown to lead to Mo2O6 formation: when P = 1 bar, a synthesis reaction involving simple molybdenum oxides (MoO, MoO2, MoO3) is the main way; when P = 1 × 10−3 bar or lower, reactions of (MoO3)n(n = 3−5) complex oxides with metallic molybdenum and molybdenum monoxide (MoO) are. |
| Databáze: | OpenAIRE |
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