Spectroscopic studies of Lewis acid-base complexes—I
| Autor: | Robert C. Taylor, Robert L. Amster |
|---|---|
| Rok vydání: | 1964 |
| Předmět: |
Infrared
Inorganic chemistry chemistry.chemical_element Isotopes of boron Boron trichloride chemistry.chemical_compound symbols.namesake chemistry symbols General Earth and Planetary Sciences Physical chemistry Boron tribromide Lewis acids and bases Boron Raman spectroscopy Boron trifluoride General Environmental Science |
| Zdroj: | Spectrochimica Acta. 20:1487-1502 |
| ISSN: | 0371-1951 |
| DOI: | 10.1016/0371-1951(64)80131-4 |
| Popis: | Infrared and Raman spectra of 1:1 complexes of trimethylamine with boron trifluoride, boron trichloride and boron tribromide have been obtained in the solid state. Samples studied included those isotopically enriched in B 10 as well as those containing the natural isotopic ratio of B 11 to B 10 . On the basis of isotopic shifts and trends of frequencies within the series, vibrational assignments of the observed frequencies are proposed. |
| Databáze: | OpenAIRE |
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