Contribution to the So-called structure temperature of the electrolyte solutions in methanol based on IR OH band-intensities
| Autor: | Matthias Fritzsche, Werner A.P. Luck |
|---|---|
| Rok vydání: | 1992 |
| Předmět: |
Overtone
Inorganic chemistry Analytical chemistry Infrared spectroscopy Electrolyte Condensed Matter Physics Sodium perchlorate Atomic and Molecular Physics and Optics Lithium perchlorate Electronic Optical and Magnetic Materials Ion chemistry.chemical_compound Solvation shell chemistry Materials Chemistry Methanol Physical and Theoretical Chemistry Spectroscopy |
| Zdroj: | Journal of Molecular Liquids. 52:211-223 |
| ISSN: | 0167-7322 |
| DOI: | 10.1016/0167-7322(92)80104-p |
| Popis: | The averaged structure temperature T str , as T with similar H-bond structure as the pure liquid, is determined of alcoholic 2.2 m solutions (anions) by IR fundamental integrated intensities. As ion series is got T str : NaClO 4 , LiClO 4 , LiCl, CsCl, CsF as similar Hofmeister ion series as in water. This method agrees qualitatively with the T str estimations by overtone absorbances and band analysis of non H-bonded OH. Studies of the concentration dependences of T str allows indications on water in the first hydration shell and establish the T str solution studies as useful tool for an average description of solution properties. |
| Databáze: | OpenAIRE |
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