Cooligomerization of carbon monoxide with cyclic olefins on supported palladium catalysts

Autor:	A. V. Chernyak, O. M. Chukanova, M. A. Smirnov, K. A. Alferov, G. P. Belov
Rok vydání:	2013
Předmět:	chemistry.chemical_classification Ketone Ethylene Polymers and Plastics Double bond chemistry.chemical_element Catalysis chemistry.chemical_compound chemistry Dicyclopentadiene Polymer chemistry Materials Chemistry Ceramics and Composites Organic chemistry Palladium Carbon monoxide Norbornene
Zdroj:	Polymer Science Series B. 55:546-550
ISSN:	1555-6123 1560-0904
DOI:	10.1134/s1560090413080022
Popis:	The cooligomerization of CO with cyclic olefins, such as norbornene, 5-vinyl-2-norbornene, and dicyclopentadiene, in toluene in the presence of supported palladium catalysts containing 2,2’-bipyridine as a ligand is studied. It is shown that, during copolymerization, opening of the double bond in a ring occurs, while in the case of 5-vinyl-2-norbornene, vinyl bond C=C is not involved in the reaction. When ethylene is added to the reaction mixture, it does not participate in polymer-chain growth. The yield of the process is commensurable with the yield attained in the case of a homogeneous catalytic system, and the conversion of olefins is as high as 47%. The copolymers in the solid state occur in the form of spiroketal structures that, during dissolution, transform into ketone structures to different extents.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d3c982cfae8dffc70f5e6350a6f30ec0 https://doi.org/10.1134/s1560090413080022 Zobrazit plný text záznamu Full text from SpringerLink