Acetylide complexes of diamagnetic gallium(III) and paramagnetic iron(III) porphyrins

Autor:	Alan L. Balch, Lechosław Latos-Grażyński, Shane L. Phillips, Bruce C. Noll
Rok vydání:	1993
Předmět:	Acetylide Inorganic chemistry chemistry.chemical_element Nuclear magnetic resonance spectroscopy Crystal structure Porphyrin Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry X-ray crystallography Tetraphenylporphyrin Lithium Physical and Theoretical Chemistry Gallium
Zdroj:	Inorganic Chemistry. 32:1124-1129
ISSN:	1520-510X 0020-1669
Popis:	Five-coordinate {(TPP)Ga III (Cœ3CR)} complexes (TPP is the dianion of tetraphenylporphyrin; A is n-Pr or Ph) and {(TTP)Fe III (Cœ3CR)} (TPP is the dianion of tetrakis(p-tolyl)porphyrin); A=n-Pr or Ph) have been obtained by the reaction of {(P)M III Cl} (M=Ga or Fe, P=porphyrin dianion) with the appropriate lithium acetylide. Red blocks of {(TPP)Ga III (Cœ3CPr n )) (C 49 H 35 GaN 4 ) crystallize in the orthorbombic space group Pna2 1 .
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d3c2da64e461d9ac7e00b9db2f33f7cf https://doi.org/10.1021/ic00059a017 Zobrazit plný text záznamu