Acetylide complexes of diamagnetic gallium(III) and paramagnetic iron(III) porphyrins
Autor: | Alan L. Balch, Lechosław Latos-Grażyński, Shane L. Phillips, Bruce C. Noll |
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Rok vydání: | 1993 |
Předmět: | |
Zdroj: | Inorganic Chemistry. 32:1124-1129 |
ISSN: | 1520-510X 0020-1669 |
Popis: | Five-coordinate {(TPP)Ga III (Cœ3CR)} complexes (TPP is the dianion of tetraphenylporphyrin; A is n-Pr or Ph) and {(TTP)Fe III (Cœ3CR)} (TPP is the dianion of tetrakis(p-tolyl)porphyrin); A=n-Pr or Ph) have been obtained by the reaction of {(P)M III Cl} (M=Ga or Fe, P=porphyrin dianion) with the appropriate lithium acetylide. Red blocks of {(TPP)Ga III (Cœ3CPr n )) (C 49 H 35 GaN 4 ) crystallize in the orthorbombic space group Pna2 1 . |
Databáze: | OpenAIRE |
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