Preparation, characterization and catalytic oxidation properties of bis-quaternary ammonium peroxotungstates and peroxomolybdates complexes

Autor:	Xianying Shi, Junfa Wei
Rok vydání:	2007
Předmět:	Aqueous solution Chemistry Halide General Chemistry Catalysis Inorganic Chemistry chemistry.chemical_compound symbols.namesake Catalytic oxidation Benzyl alcohol symbols Organic chemistry Ammonium Raman spectroscopy Hydrogen peroxide
Zdroj:	Applied Organometallic Chemistry. 21:172-176
ISSN:	1099-0739 0268-2605
DOI:	10.1002/aoc.1196
Popis:	Several novel kinds of bis-quaternary ammonium peroxotungstates and peroxomolybdates, such as PhCH2N(CH2CH2)3NCH2Ph[W2O3(O2)4], PhCH2N(CH2CH2)3NCH2Ph [Mo2O3(O2)4], [PhCH2(CH3)2NCH2]2[W2O3(O2)4] and [PhCH2(CH3)2NCH2]2[Mo2O3(O2)4], have been synthesized and characterized by elemental analysis, IR and Raman spectroscopy. Their catalytic properties in mild oxidation of benzyl alcohol and ring-substituted benzyl alcohols were investigated with aqueous 30% H2O2 under halide- and organic solvent-free conditions. Copyright © 2007 John Wiley & Sons, Ltd.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d377ffa26c0feba44c7cbb335ba3479d https://doi.org/10.1002/aoc.1196 Zobrazit plný text záznamu Plný text