Composition of Sulfur Compounds in Asphaltic–Resinous Sediments and Oil Components in Petroleum From the Usinsk Oil Field
| Autor: | Tatiana V. Cheshkova, E. Yu. Kovalenko, T. A. Sagachenko, R. S. Min, S. S. Yanovskaya, V. P. Sergun |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
chemistry.chemical_classification
Sulfide General Chemical Engineering Monobasic acid Energy Engineering and Power Technology chemistry.chemical_element 02 engineering and technology General Chemistry 01 natural sciences Sulfur Decomposition 010406 physical chemistry 0104 chemical sciences chemistry.chemical_compound Fuel Technology 020401 chemical engineering chemistry Shale oil Petroleum Organic chemistry 0204 chemical engineering Organosulfur compounds Asphaltene |
| Zdroj: | Chemistry and Technology of Fuels and Oils. 52:293-299 |
| ISSN: | 1573-8310 0009-3092 |
| DOI: | 10.1007/s10553-016-0706-1 |
| Popis: | The composition of the structural fragments of resinous and asphaltic molecules in Usinsk heavy oil containing C – S sulfide bonds and of organosulfur compounds in the oily components of this petroleum was studied. The composition of the sulfur–containing fragments of the asphaltenes was studied separately for their low– and high–molecularweight fractions and occluded maltenes. Alkanes, naphthenes, mono and polycyclic aromatic hydrocarbons, dibenzothiophenes, and monobasic aliphatic acids were found in the fragments of the resinous–asphaltic compounds linked by sulfide bridges. The sulfur–containing structures of the oily components are represented by alkyl–substituted thiophenes, benzo, dibenzo, and benzonaphthothiophenes, and bicyclic sulfides. Heat treatment of this petroleum leads to decomposition of the resins and asphaltenes at the sulfide bridges and transition of individual fragments in the distillates, which must be taken into account in upgrading procedures. |
| Databáze: | OpenAIRE |
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