An Extremely Porous Hydrogen-Bonded Framework Composed of d -Penicillaminato CoIII 2 AuI 3 Complex Anions and Aqua Cobalt(II) Cations: Formation and Stepwise Structural Transformation
| Autor: | Takumi Konno, Sireenart Surinwong, Bunlawee Yotnoi, Nobuto Yoshinari |
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| Rok vydání: | 2015 |
| Předmět: |
Hydrogen
010405 organic chemistry Organic Chemistry Ionic bonding chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Biochemistry 0104 chemical sciences Crystallography chemistry.chemical_compound Adsorption chemistry Selective adsorption X-ray crystallography Carboxylate Porosity Cobalt |
| Zdroj: | Chemistry - An Asian Journal. 11:486-490 |
| ISSN: | 1861-4728 |
| DOI: | 10.1002/asia.201501352 |
| Popis: | A unique example of a hydrogen-bonded ionic solid with a porosity of 80 %, [Co(H2O)6]3 [Co2Au3 (d-pen-N,S)6]2 (1; d-H2 pen=d-penicillamine), composed of [Co(H2O)6](2+) cations and [Co2Au3 (d-pen-N,S)6 ](3-) anions, is reported. Solid 1 was kinetically produced and was then transformed stepwise into two more thermodynamically stable solids with lower porosities, [Co(H2O)4 ][Co(H2O)6]2 [Co2Au3 (d-pen-N,S)6]2 (2) and [Co(H2O)4]3 [Co2 Au3 (d-pen-N,S)6]2 (3), through the coordination of the free carboxylate groups in [Co2Au3 (d-pen-N,S)6](3-) to Co(II) centers. Solids 1-3 were structurally characterized, and the selective adsorption of small molecules into their pores was investigated. |
| Databáze: | OpenAIRE |
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