Thermodynamic Investigation of Dimethyl Sulfoxide Binary Mixtures at 293.15 and 313.15 K

Autor:	Maria M. Palaiologou, Nikos G. Tsierkezos, George K. Arianas
Rok vydání:	2006
Předmět:	chemistry.chemical_classification Ketone Isentropic process Dimethyl sulfoxide Biophysics Cyclohexanone Thermodynamics Biochemistry chemistry.chemical_compound chemistry Speed of sound Compressibility Acetone Methanol Physical and Theoretical Chemistry Molecular Biology
Zdroj:	Journal of Solution Chemistry. 35:1551-1565
ISSN:	1572-8927 0095-9782
DOI:	10.1007/s10953-006-9082-5
Popis:	Densities (ρ), speeds of sound (u), and isentropic compressibilities (kS) of binary mixtures of dimethyl sulfoxide (DMSO) with water, methanol, ethanol, 1-propanol, 2-propanol, acetone and cyclohexanone have been measured over the entire composition range at 293.15 and 313.15 K. The excess molar volumes (VE), the deviations in speed of sound (uE) and the deviations in isentropic compressibility (kSE) have been determined. The VE, uE and kSE values were fitted by the Redlich-Kister polynomial equation and the Ak coefficients as well as the standard deviations (d) between the calculated and experimental values have been derived. The results obtained are discussed from the viewpoint of the existence of interactions between the components of the binary mixtures.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d312b9223fbde52fec900c337be62de7 https://doi.org/10.1007/s10953-006-9082-5 Zobrazit plný text záznamu Full text from SpringerLink