(Z/E)-photoisomerization of C40-carotenoids by iodine

Autor:	Péter Molnár, J. Szabolcs
Rok vydání:	1993
Předmět:	Zeaxanthin chemistry.chemical_classification chemistry.chemical_compound Photoisomerization Chemistry Stereochemistry Light energy chemistry.chemical_element Iodine Carotenoid Violaxanthin
Zdroj:	J. Chem. Soc., Perkin Trans. 2. :261-266
ISSN:	1364-5471 0300-9580
Popis:	The compositions of stereoisomeric mixtures of β-carotene (1), zeaxanthin (2), physaliene (3), natural violaxanthin (4), ‘semi-synthetic’ violaxanthin (5), capsorubin (6), capsanthin (7) and lutein-epoxide (8) have been investigated. The effect of end groups with different structures and stereochemistry on the cis-trans equilibrium, the rates of photo-induced cis–trans rearrangement of the zeaxanthin (2) set, and the ‘specific rate’(per unit light energy at a given wavelength) for several 13-cis carotenoids (2, 4, 6, 7, 9) have been determined.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d2fc88c4f5f9d7a41db65d1b5c658c82 https://doi.org/10.1039/p29930000261 Zobrazit plný text záznamu