'Highly Destabilized Carbocations,' Generation and Rearrangements in the Reaction of 8,9,10,11-Tetrahydrocyclohepta[a]phenalen-6(12H)-one-12-ol and -7(12H)-one-12-ol with Sulfuric Acid

Autor:	Yoshiyuki Takahashi, Masahiro Murotani, Tomoaki Hidenaga, Ichiro Shimao, Shigeyasu Kuroda, Syuzi Hirooka, Toshiaki Ozaki, Masaki Yamada, Guan-Jin Guan, Masayuki Saka
Rok vydání:	1992
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Ketone chemistry Organic chemistry Sulfuric acid General Chemistry Carbocation Enone Vicinal
Zdroj:	Chemistry Letters. 21:719-722
ISSN:	1348-0715 0366-7022
DOI:	10.1246/cl.1992.719
Popis:	The reaction of 8,9,10,11-Tetrahydrocyclohepta[a]phenalen-6(12H)-one-12-ol and -7(12H)-one-12-ol with H2SO4 gave skeletally rearranged 9- and 10-methylbenz[de]anthracen-6-one and -7-one via destabilized vicinal dications.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d2ef3b9e9fe33f5575f128c0266bbc0c https://doi.org/10.1246/cl.1992.719 Zobrazit plný text záznamu