Vanadium-catalyzed Selective Oxidation of Sulfides to Sulfoxides and Sulfones with H2O2

Autor:	Qian F. Zhang, Min Chen, Ai Q. Jia, Wen-Yan Zhou, Pei-Zhi Zhang
Rok vydání:	2021
Předmět:	chemistry.chemical_compound chemistry Organic Chemistry Vanadium chemistry.chemical_element Organic chemistry Gas chromatography Sulfone Catalysis
Zdroj:	Russian Journal of Organic Chemistry. 57:816-824
ISSN:	1608-3393 1070-4280
DOI:	10.1134/s1070428021050080
Popis:	A direct selective approach to the oxidation of sulfides to sulfoxides and sulfones with H2O2 in moderate to good yields is developed. The reaction proceeds in the presence of 2 mol % of VO(acac)2 at room temperature. All sulfoxides and sulfones were detected by gas chromatography, and the molecular structures of 2-methylbenzyl 4-methylphenyl sulfone, 4-methylbenzyl 4-methylphenyl sulfone, 2-bromobenzyl 4-methylphenyl sulfone, and 4-tert-butylbenzyl benzyl sulfone were determined by single crystal X-ray crystallography.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d2e8c120aeffd7f646cdc8f496580072 https://doi.org/10.1134/s1070428021050080 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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