Chloroplatinic acid as a catalyst for the addition of silanes containing silicon-attached hydrogen to unsaturated compounds

Autor:	A. D. Petrov, V. A. Ponomarenko, V. G. Cherkaev, N. A. Zadorozhnyi
Rok vydání:	1958
Předmět:	Propene chemistry.chemical_compound Addition reaction Silanes Ethylene Acetylene chemistry Inorganic chemistry chemistry.chemical_element General Chemistry Platinum Chloroplatinic acid Catalysis
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 7:238-240
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf01168537
Popis:	1. Addition reactions of CH3SiHCl2 were carried out in presence of chloroplatinic acid with ethylene, propene, and acetylene at room temperature and with CH2 = CF2 and CF2 = CF2 at 160°. 2. It was shown that, as compared with reaction in presence of platinum on carriers, in the case of CH2 = CF2 the yield of addition products was increased by a factor of 3–4. whereas in the case of CH2=CH2, CH2 = = CH- CH3 and CH ≡ CH almost quantitative yields were obtained.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d2e3b2a677bca160a2f2dde77add6c23 https://doi.org/10.1007/bf01168537 Zobrazit plný text záznamu Full text from SpringerLink