Conformation of cyclohexane ring in some polycyclic molecules
Autor: | N. A. Alekperov, Anatoly N. Vereshchagin, R. S. Salakhova, M. S. Salakhov, S. G. Vul'fson, A. P. Timosheva, N. É. Musaeva |
---|---|
Rok vydání: | 1975 |
Předmět: | |
Zdroj: | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 24:785-790 |
ISSN: | 1573-9171 0568-5230 |
DOI: | 10.1007/bf00920694 |
Popis: | 1. When the cyclohexane ring is trans-condensed with a five-membered anhydride ring and a bicyclic system the C-C bonds of the bicyclic system occupy equatorial positions. 2. The stereochemistry of the diene synthesis of hexachlorocyclopentadiene with the anhydrides of cis- and trans-3-methyl-4-cyclohexene-1,2-dicarboxylic acids is determined by the configuration of the methyl group. 3. The addition of maleic anhydride to the diene system of the anhydride of 1,2,3,4-tetracehlorobicyclo[4.4.0]decadiene-8,9-dicarboxylic acid goes in the trans-position to the bonds of the cyclohexane ring. |
Databáze: | OpenAIRE |
Externí odkaz: |