Magnetic properties and crystal structure of a 1D alternating chain copper(II) compound with bridging fumarate and trans-oxamidate ligands
| Autor: | Fang Ming Miao, Zhong-Ning Chen, Wen Xia Tang, Jing Ling Wang |
|---|---|
| Rok vydání: | 1994 |
| Předmět: |
chemistry.chemical_classification
Oxamide Inorganic chemistry Exchange interaction chemistry.chemical_element Crystal structure Polymer Copper Ion Inorganic Chemistry Copper atom chemistry.chemical_compound Crystallography chemistry Materials Chemistry Antiferromagnetism Physical and Theoretical Chemistry |
| Zdroj: | Polyhedron. 13:2543-2548 |
| ISSN: | 0277-5387 |
| DOI: | 10.1016/s0277-5387(00)83097-1 |
| Popis: | The complex polymer [Cu2(oxap)(fum)]n·5nH2O, where oxap and fum are dianions of N,N′-bis(2-aminopropyl)oxamide and of fumarate, respectively, was prepared and characterized by means of X-ray crystallography, magnetic and spectroscopic measurements. The structure of this compound consists of alternating chains of copper(II) ions bridged by both oxap and fumarate ligands. The central copper atom is located in an approximately square planar environment. The compound exhibits strong anti-ferromagnetic coupling with J = −390 cm−1, due to the efficiency of the oxamidato bridge in propagating antiferromagnetic exchange interaction between copper(II) ions which are separated by more than 5.2 A. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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