Iron-Catalyzed Borylation of Alkyl, Allyl, and Aryl Halides: Isolation of an Iron(I) Boryl Complex

Autor:	Robin B. Bedford, Damien Martin Murphy, Dominic R. Pye, Timothy Gallagher, Peter Brenner, Emma Carter
Rok vydání:	2014
Předmět:	chemistry.chemical_classification Aryl Iron catalyzed Organic Chemistry Halide Medicinal chemistry Borylation Inorganic Chemistry chemistry.chemical_compound chemistry Organic chemistry Physical and Theoretical Chemistry Phosphine Alkyl
Zdroj:	Organometallics. 33:5940-5943
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om500847j
Popis:	Activation of B2pin2 with tBuLi facilitates the Fe-catalyzed borylation of alkyl, allyl, benzyl, and aryl halides via the formation of Li[B2pin2(tBu)] (1). The reaction of 1 with a representative iron phosphine precatalyst generates the unique iron(I) boryl complex [Fe(Bpin)(dpbz)2] (2).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d2afa9949b0e3bb914e4bf42b7314ea0 https://doi.org/10.1021/om500847j Zobrazit plný text záznamu