Chiral mononuclear Dy(III) complex based on pyrrolidine-dithiocarboxylate S-donors with field-induced single-ion magnet behavior

Autor:	Yun-Wu Li, Cai-Ming Liu, Sui-Jun Liu, Fu-Yong Liang, He-Rui Wen, Kai Yang, Xin-Rong Xie
Rok vydání:	2018
Předmět:	Field (physics) Single ion 010405 organic chemistry 010402 general chemistry 01 natural sciences Pyrrolidine 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry Magnet Materials Chemistry Magnetic relaxation Physical and Theoretical Chemistry
Zdroj:	Inorganica Chimica Acta. 473:145-151
ISSN:	0020-1693
DOI:	10.1016/j.ica.2017.12.035
Popis:	A new chiral mononuclear Dy(III) complex, [Dy((-)-pbipy)(pdtc)3] (1) (pbipy = 4,5-pinene-2,2′-bipyridine, pdtc = pyrrolidine-dithiocarbamate) has been synthesized and structurally characterized. Magnetic studies show that complex 1 exhibits field-induced single-ion magnet behavior with τ0 = 4.2 × 10−7 s and Ueff/k = 56.7 K, which is the first example of homochiral complex derived from S-donor pyrrolidine-dithiocarboxylate with slow magnetic relaxation.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d28e9b348bc6d26bf9e23e0375ae13e2 https://doi.org/10.1016/j.ica.2017.12.035 Zobrazit plný text záznamu Full Text from ScienceDirect