The importance of accurate and precise molecular weight measurement in pulsed-laser polymerization

Autor:	Thomas P. Davis, Michael D. Zammit
Rok vydání:	1996
Předmět:	Pulsed laser Work (thermodynamics) Polymers and Plastics Polymerization Calibration curve Chemistry Organic Chemistry Size-exclusion chromatography Materials Chemistry Analytical chemistry Condensed Matter Physics Mass spectrometry
Zdroj:	Macromolecular Symposia. 111:243-252
ISSN:	1022-1360
DOI:	10.1002/masy.19961110122
Popis:	Molecular weight distributions generated by pulsed-laser polymerization have been determined experimentally using multi-detector size exclusion chromatography (SEC). The conditions for accurate and precise SEC have been defined. The importance of the inter-detector delay (IDD) is stressed and two different methods of defining IDD are compared. In addition this work highlights the problems associated with the use of Mark-Houwink constants in constructing a universal calibration curve. Some preliminary results obtained from matrix-assisted-laser-desorption-ionisation mass spectrometry are also presented.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d28e14bd356598d5d17934630f812b00 https://doi.org/10.1002/masy.19961110122 Zobrazit plný text záznamu Plný text