X-ray photoelectron study of the structure and composition of organometal cluster systems
| Autor: | I. N. Shabanova, V. I. Kodolov, N. V. Keller, S. N. Babushkina, E. I. Chirkova |
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| Rok vydání: | 1998 |
| Předmět: |
Solid-state physics
Photoemission spectroscopy Chemistry Acetylacetone Inorganic chemistry X-ray chemistry.chemical_element Copper Inorganic Chemistry Metal Crystallography chemistry.chemical_compound visual_art Materials Chemistry visual_art.visual_art_medium Cluster (physics) Physical and Theoretical Chemistry Spectroscopy |
| Zdroj: | Journal of Structural Chemistry. 39:912-916 |
| ISSN: | 1573-8779 0022-4766 |
| Popis: | This paper gives the results of the study of the structure and composition of copper- and cobalt-containing complex compounds synthesized using acetylacetone and triethyleneglycoldimethacrylate as complexons. It was established by X-ray photoelectron, IR, UV, and ESR spectroscopy that the cluster nuclei differ in size from each other by about a factor of three. When acetylacetonate is used as a complexon, the nature of the metal determines the character of interactions during structure formation of cluster systems. In the case of triethyleneglycoldimethacrylate, the character of metal-complexon interactions is determined from the variation of the X-ray photoelectron spectrum of oxygen. |
| Databáze: | OpenAIRE |
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