Structure of Rubidium Borosilicate Glasses Studied by Nuclear Magnetic Resonance Spectroscopy
| Autor: | P. M. Tolstoi, V. E. Eremyashev, Anton S. Mazur, L. M. Osipova |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
010302 applied physics
Materials science Borosilicate glass General Chemical Engineering Metals and Alloys chemistry.chemical_element 02 engineering and technology Nuclear magnetic resonance spectroscopy 021001 nanoscience & nanotechnology 01 natural sciences Rubidium Ion Inorganic Chemistry Differential scanning calorimetry chemistry 0103 physical sciences Materials Chemistry Physical chemistry 0210 nano-technology Glass transition Boron Spectroscopy |
| Zdroj: | Inorganic Materials. 55:500-505 |
| ISSN: | 1608-3172 0020-1685 |
| Popis: | We present results of an 11B and 29Si nuclear magnetic resonance (NMR) spectroscopy study of the local anion structure of a series of borosilicate glasses in the Rb2O–B2O3–SiO2 system with different R = [Rb2O]/[B2O3] and K = [SiO2]/[B2O3] molar ratios. Relative integrated intensities of NMR lines are used to evaluate the fractions of boron atoms in three- and fourfold coordinations and the concentrations of various types of Qn silicate units. Comparison of the present data on the anion structure of the Rb2O–B2O3–SiO2 glasses studied here and data for previously studied glasses of analogous compositions in the Cs2O–B2O3–SiO2 system demonstrates that the difference in the degree of depolymerization in the anion structure of the glasses in these two systems is most pronounced at R = 1 and K = 2. At other values of these composition parameters (R = 0.43 and K = 1.43 or R = 2.33 and K = 3.33), the glasses with the compositions studied in the Rb2O–B2O3–SiO2 and Cs2O–B2O3–SiO2 systems are rather similar in local anion structure. The observed structural distinctions between the glasses make it possible to find out why they differ in glass transition temperature, as shown in a previous study by differential scanning calorimetry. |
| Databáze: | OpenAIRE |
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