Nucleophilic addition reactions to nitrilium derivatives [B12H11NCCH3]− and [B12H11NCCH2CH3]−. Synthesis and structures of closo-dodecaborate-based iminols, amides and amidines

Autor: Julia Laskova, Ivan Ananiev, Irina Kosenko, Alexander Serdyukov, Marina Stogniy, Igor Sivaev, Mikhail Grin, Andrey Semioshkin, Vladimir I. Bregadze
Rok vydání: 2022
Předmět:
Zdroj: Dalton Transactions. 51:3051-3059
ISSN: 1477-9234
1477-9226
DOI: 10.1039/d1dt04174f
Popis: Nucleophilic addition reactions to the activated triple bond of the nitrilium derivatives of the closo-dodecaborate anion were studied.
Databáze: OpenAIRE