Copper(II)-Promoted Cascade Synthesis of 2-Aminobenzothiazoles Starting from 2-Iodoanilines and Sodium Dithiocarbamates

Autor:	Shi-Bo Zhang, Xing Liu, Hui Zhu, Zhi-Bing Dong, Yu Cheng, Han-Ying Peng
Rok vydání:	2018
Předmět:	Reaction conditions 010405 organic chemistry Sodium Organic Chemistry chemistry.chemical_element Homogeneous catalysis 010402 general chemistry 01 natural sciences Combinatorial chemistry Copper 0104 chemical sciences chemistry Cascade Physical and Theoretical Chemistry
Zdroj:	European Journal of Organic Chemistry. 2018:5711-5716
ISSN:	1434-193X
DOI:	10.1002/ejoc.201801122
Popis:	A facile and efficient formation of 2-aminobenzothiazoles by a copper(II)-promoted one-pot cascade process was developed. The desired 2-aminobenzothiazoles were synthesized in good to excellent yields (up to 97 %) in the presence of Cu(OAc)(2) and K2CO3, a variety of functional groups on 2-iodoanilines could be tolerated. The method features ligand-free and mild reaction conditions and good yields, illustrating its practical synthetic value in some potentially biologically active compounds.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d2324438c0b217450b7ef1a00c6942ef https://doi.org/10.1002/ejoc.201801122 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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