Wired Porous Cathode Materials: A Novel Concept for Synthesis of LiFePO4
| Autor: | Robert Dominko, Marjan Bele, Jean-Michel Goupil, Miran Gaberscek, Iztok Arčon, Janez Jamnik, Darko Hanzel |
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| Rok vydání: | 2007 |
| Předmět: | |
| Zdroj: | Chemistry of Materials. 19:2960-2969 |
| ISSN: | 1520-5002 0897-4756 |
| DOI: | 10.1021/cm062843g |
| Popis: | To increase the power density of battery materials, without significantly affecting their main advantage of a high energy density, novel material architectures need to be developed. Using the example of LiFePO4, we demonstrate a simple, sol−gel-based route that leads to large (up to 20 μm) primary LiFePO4 particles, each of which contains hierarchically organized pores in the meso and macro range. As the pores are formed due to vigorous gas evolution (mainly CO and CO2) during degradation of a citrate precursor, they are perfectly interconnected within each particle. Elementary carbon, the other citrate-degradation product, is deposited on the walls of emerging pores. The superposition of a continuous 1−2 nm thick carbon film (electron conductor) on pores (ion conductor when filled with electrolyte) represents a unique architecture in which the electrons and ions are simultaneously supplied to the site of insertion in the particle interior. The material can operate at current rates up to 50 C while preser... |
| Databáze: | OpenAIRE |
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