Broadband dielectric spectroscopy of protic ethylammonium-based ionic liquids synthetized with different anions
| Autor: | P. R. G. Fernandes, Lúcio Cardozo-Filho, Helen Mazzer |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Permittivity
Materials science 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Atomic and Molecular Physics and Optics 0104 chemical sciences Electronic Optical and Magnetic Materials Ion chemistry.chemical_compound chemistry Electrical resistivity and conductivity Ionic liquid Materials Chemistry Physical chemistry Physical and Theoretical Chemistry 0210 nano-technology Spectroscopy Broadband dielectric spectroscopy |
| Zdroj: | Journal of Molecular Liquids. 269:556-563 |
| ISSN: | 0167-7322 |
| DOI: | 10.1016/j.molliq.2018.08.076 |
| Popis: | In this work, we present the synthesis of the of 2‑Hydroxy ethylammonium Lactate (HELa) and of 2‑Hydroxy ethylammonium Citrate (HECi) protic ionic liquids and their electric characterization by broadband dielectric spectroscopy. The complex permittivity e∗ and electrical conductivity σ∗ of HELa and HECi as a function of frequency and of temperature are obtained. The experimental results are discussed considering the type of anion in each ionic liquid. In the high frequency range (f > 1KHz), at room temperature (T ~25 °C), the HELa protic ionic liquid has been shown an electric conductivity higher than that formed by citrate anion. |
| Databáze: | OpenAIRE |
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