Synthesis of tris[2-(2-furyl)ethyl]phosphine its chalcogenides and Pdii complex

Autor: Yurii V. Gatilov, Nina K. Gusarova, Alexander V. Artem'ev, Anastasiya O. Sutyrina, Boris A. Trofimov
Rok vydání: 2016
Předmět:
Zdroj: Mendeleev Communications. 26:314-316
ISSN: 0959-9436
DOI: 10.1016/j.mencom.2016.07.016
Popis: Nucleophilic addition of PH3 to 2-vinylfuran in the KOH/DMSO(H2O) suspension affords 65% of tris[2-(2-furyl)ethyl]-phosphine, whose treatment with H2O2, Se or PdCl gives the corresponding phosphine oxide, selenide and complex of trans-[Pd(L)2Cl2] type in good to excellent yields.
Databáze: OpenAIRE