Synthesis of tris[2-(2-furyl)ethyl]phosphine its chalcogenides and Pdii complex
Autor: | Yurii V. Gatilov, Nina K. Gusarova, Alexander V. Artem'ev, Anastasiya O. Sutyrina, Boris A. Trofimov |
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Rok vydání: | 2016 |
Předmět: | |
Zdroj: | Mendeleev Communications. 26:314-316 |
ISSN: | 0959-9436 |
DOI: | 10.1016/j.mencom.2016.07.016 |
Popis: | Nucleophilic addition of PH3 to 2-vinylfuran in the KOH/DMSO(H2O) suspension affords 65% of tris[2-(2-furyl)ethyl]-phosphine, whose treatment with H2O2, Se or PdCl gives the corresponding phosphine oxide, selenide and complex of trans-[Pd(L)2Cl2] type in good to excellent yields. |
Databáze: | OpenAIRE |
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