Oxidative addition of 2,2′-dithiosalicylic acid to the cluster [Os3(CO)10)(CH3CN)2]

Autor:	Siu-Ming Lee, Wing Tak Wong
Rok vydání:	1996
Předmět:	Structure analysis Chemistry General Chemistry Condensed Matter Physics Biochemistry Oxidative addition Medicinal chemistry Catalysis Crystallography Yield (chemistry) Cluster (physics) General Materials Science Dithiosalicylic acid Single crystal
Zdroj:	Journal of Cluster Science. 7:37-47
ISSN:	1572-8862 1040-7278
DOI:	10.1007/bf01166175
Popis:	The reaction of 2,2'-dithiosalicylic acid with two equivalents of [Os3(CO)10 (CH3CN)] in THF at −78°C yields yellow crystals of [{Os3(CO)10(μ-H)}2 (O2CC6H4S)2] 1 in moderate yield. Hydrogenetaion of 1 in refluxing CHCl3 affords [Os3(CO)1(μ-H)(O2CC6H5)] 2 in good yield. Structures of 1 and 2 have been established by single crystal X-ray structure analysis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d1c928ffe2f9c5734b60ff850d32b01e https://doi.org/10.1007/bf01166175 Zobrazit plný text záznamu Full text from SpringerLink