Nano palladium catalyzed C(sp3) H bonds arylation by a transient directing strategy
| Autor: | Chaolumen Bai, Yong-Sheng Bao, Dan Liu, Jianxia Chen, Hongpeng Ma |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
inorganic chemicals
Chemistry Aryl chemistry.chemical_element 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Highly selective 01 natural sciences Combinatorial chemistry 0104 chemical sciences Catalysis Metal chemistry.chemical_compound Catalytic cycle X-ray photoelectron spectroscopy visual_art Nano visual_art.visual_art_medium 0210 nano-technology Palladium |
| Zdroj: | Chinese Chemical Letters. 32:465-469 |
| ISSN: | 1001-8417 |
| Popis: | Reported herein is the first example of heterogeneous palladium catalyzed C(sp3)-H bonds arylation by a transient-ligand-directed strategy. Using supported palladium (metallic state) nanopariticles as catalyst, a wide range of aryl iodides undergo the coupling with various o-methylbenzaldehyde derivatives to assemble a library of highly selective and functionalized o-benzylbenzaldehydes. The stability of the catalyst was easily recovered four runs without significant loss of activity. The XPS analysis of the catalyst before and after reaction indicated that the reaction might be carried out by a catalytic cycle starting with Pd0. |
| Databáze: | OpenAIRE |
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