Dissolution of a transparent cross-linked polymer monolith in water by oxidative de-crosslinking
| Autor: | Kazuya Yanaze, Moe Kaneko, Nobuhiro Kihara, Satoshi Yokoyama |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
chemistry.chemical_classification
010407 polymers geography geography.geographical_feature_category Polymers and Plastics Oxidative degradation Chemistry Oxidative phosphorylation Polymer 01 natural sciences 0104 chemical sciences Sodium hypochlorite solution Chemical engineering Materials Chemistry Copolymer Moiety Monolith Dissolution |
| Zdroj: | Polymer Journal. 51:1007-1013 |
| ISSN: | 1349-0540 0032-3896 |
| Popis: | Bulk copolymerization of bis(acryloylhydrazine) with N,N-dimethylacrylamide or N,N-diethylacrylamide yielded a transparent crosslinked polymer monolith. Upon treatment with a sodium hypochlorite solution, the cross-linked monolith dissolved in water by de-crosslinking via oxidative degradation of the diacylhydrazine moiety. Bulk copolymerization of bis(acryloylhydrazine) with N,N-dimethylacrylamide or N,N-diethylacrylamide yielded a transparent cross-linked polymer monolith. Upon treatment with a sodium hypochlorite solution, the cross-linked monolith dissolved in water by de-crosslinking via oxidative degradation of the diacylhydrazine moiety. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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